were fabricated on AT cut quartz crystal based substrates by spin coating. Atomic Force Microscopy (AFM) was used for topography analysis; QCM was used for quantitative analysis. Film thickness data suggests that a bilayer DLPC is 4.3 nm and a bilayer DSPC is 5.8 nm thick. Quantum mechanical calculations of the geometry and electronic structure were performed for compound 37; the known phenylene analogue 42 was calculated at the same level for comparison. The results show that the energies of both HOMO and LUMO orbitals of 37 are decreased compared to 42. The calculated value of the HOMO LUMO gap of 37 (3.56 eV) is close to that estimated from the red edge of the longest wavelength absorption (382 nm = 3.25 eV)..
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