a methodology was investigated in which cross linking could occur via a free radical mechanism involving hemolytic bond cleavage of sterically demanding groups. A number of monomers containing a bulky pendant group were prepared and were investigated in order to determine their suitability to undergo copolymerisation with vinylidene fluoride. Copolymers obtained in this way were then examined to determine whether polymer radicals could be produced by thermally induced hemolytic bond scission of sites involving the sterically crowded groups.
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