whereas larger NPs (10 and 20 nm) caused irreversible changes to the lipid membrane. The investigation on the effect of NPs surface charge on NPs membrane interactions with complex thiolated polymeric AuNPs revealed that the AuNPs containing bulky aromatic cationic ligands were not able to penetrate through tBLM models whilst aliphatic cationic ligands altered the membrane's architecture as they penetrated through.
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